FUNDAMENTAL DIFFERENCES
The basic difference between
petroleum-based and synthetic lubricants is the base fluid.
Petroleum-base lubricants are extracted from natural crude oil, and must
be refined, desalted, dewaxed, and distilled from crude feedstock. These
base fluids are made up of a great variety of naturally occurring
hydrocarbons arranged in many molecular configurations. There are
families of hydrocarbons that are segregated throughout the refining of
crude oil.
Synthetic lubricants, which have been
in existence for more than half of the roughly 100 years during which
time petroleum-based lubricants have been used by major industrial
plants, are developed in research laboratories. When something is
synthetic, it has been created through the combination of separate parts
into a whole (synthesized). As a chemical term, synthetic refers
to a compound formed through a chemical reaction that did not occur
naturally. The entire molecular structure of a synthetic lubricant is
determined by tailored, tightly controlled chemical reactions; hence,
the higher cost of synthetic lubricants.
Different synthetic lubricants are
made from different base fluids. Table 1 below compares the properties
of four (4) different base stocks. Here are some facts about three (3)
common synthetic base fluids.
ORGANIC ESTERS
are made up of dibasic acid esters or polyol
esters. Both can be used at temperatures exceeding 400°F. Dibasic acids
are particularly effective as base fluids for compressor lubricants,
while polyol esters are used in lubricants for industrial chains and gas
turbines.
PHOSPHATE ESTERS
serve as the base fluid for many lubricants
used where there is a risk of fire.
SYNTHETIC HYDROCARBON FLUIDS (SHF)
are manufactured by combining hydrocarbons of
butylene or ethylene to create a polyalphaolefin (PAO) base fluid. SHF
bases are used in numerous applications because of their superior
temperature range and lubricating properties.
TABLE 1 BASE FLUID PROPERTIES |
|
|
BASE FLUID |
Property |
Petrolium Oil |
Organic Esters |
Phosphate Esters |
PAO |
|
Lubricity |
Good |
Excellent |
Fair |
Good |
Elastomer Compatibility |
Good |
Fair |
Poor |
Excellent |
Additive Response |
Good |
Excellent |
Good |
Fair |
Volatility |
Fair |
Excellent |
Fair |
Excellent |
Oxidation Stability |
Fair |
Excellent |
Fair |
Excellent |
Compatibility with Petroleum |
Excellent |
Excellent |
Good |
Excellent |
Temperature Range |
Fair |
Excellent |
Fair |
Excellent |
Fire Resistance |
Poor |
Good |
Excellent |
Fair |
|
ADVANTAGES of SYNTHETICS
There is no question that synthetic
lubricants have demonstrated advantages over petroleum-based products in
several areas.
BEST SYNTHETIC LUBE APPLICATIONS
No matter what size the plant, there
are several applications for which synthetic lubricants are highly
recommended.
Air Compressor Duty. Nearly every air
compressor manufacturer recommends draining a synthetic lubricant after
8,000 hours, as opposed to 1,000 hours with a petroleum-based lubricant.
Aside from drain intervals, air compressors require a lubricant which
provides excellent oxidation resistance, because they compress air at
very high temperatures, often 250°F and higher.
Extreme Temperature Duty. Synthetic
lubricants have superior viscosity-to-temperature characteristics that
make them especially suitable for use in refrigerators, ovens, or plants
in hot or cold climates.
Continuous Duty. When equipment
shutdowns for oil changes absolutely must be minimized, synthetics are
the obvious choice because they need to be changed so infrequently.
Plants that run an assembly line-type process -- meaning if one piece of
equipment is down, all production stops -- may find the use of synthetic
lubricants most economical.
BEST PETROLEUM LUBE APPLICATIONS
Here are several applications where
petroleum-based lubricants shine.
High Consumption Applications.
The classic example is equipment that has accumulated very many
operating hours and become worn, resulting in increased lubricant
consumption. Because of their low initial cost, petroleum-based
lubricants are the much more economical option in high-consumption
applications.
Once-Through Applications.
Petroleum-based lubricants are always the economical option in equipment
that has no reservoir -- applications in which oil sprays into the
cylinder, lubricates the piston, and then blows down line as in gas
compressors.
Product Contamination Applications.
In a natural gas liquid processing plant, neither synthetic nor
petroleum-based lubricants can completely escape contamination by the
final product when it enters the crankcase.
The resulting need for frequent oil
changes points to petroleum-based lubricants because of their lesser
unit cost.
Very Dirty or Dusty Environments.
Unlike automotive motor oils that are designed to suspend dirt and
deposits, industrial oils are designed to clean, cool, and seal the
equipment they are lubricating. Neither synthetic nor petroleum-based
lubricants are designed to suspend dirt and dust blown into the
equipment from the exterior. Therefore, petroleum-based lubricants are
the cost-effective choice for equipment operated in extremely dirty or
dusty environments.
OIL ANALYSIS IMPROVES MAINTENANCE
Oil analysis should be a key tool in
any preventive maintenance program, whether the plan incorporates
synthetic or petroleum-based lubricants. There are two main components
of oil analysis; spectrometric analysis and physical tests.
Spectrometric Analysis
Spectrometric analysis is used to
measure the levels of metals in the oil, and aids in determining
equipment condition. With this information, plant maintenance
supervisors can plan downtime for inspection and/or repairs.
Equipment interior wear conditions and
resulting oil contamination should be monitored, regardless of the
lubricant used. It's also important to use spectrometric analysis to
check the condition of all equipment scheduled to be switched to
synthetic lubricants before making the switch.
Physical Tests
Results of physical tests help
determine how long oil can remain in equipment.
Viscosity.
The internal resistance to flow of a lubricant is perhaps the key
determining factor in whether an oil needs to be changed.
Particle Count.
A high particle count when measuring solids in oil, such as fuel soot
and sludge, often indicates that a new oil filter is needed.
Nitration.
An indication of contaminants from accumulation of combustion
byproducts, such as abnormal blow-by, is also a signal for a change.
OIL DRAIN SAVINGS:
AN EXAMPLE
Consider the lubrication of two
identical pieces of equipment in a plastic extrusion plant over an
8,000-hour period. Each machine has a 20-gallon sump. (See Table 2
below).
Machine A is lubricated with 20
gallons of synthetic lubricant, which is drained and replaced at a
recommended interval of 8,000 hours. Lubricant cost is $25.00 per gallon
for a total 8,000-hour expenditure of $500.00 (20 gallons x $25.00 x 1
oil change).
Machine B is lubricated with 20
gallons of petroleum-based lubricant, which is drained and replaced at
factory-recommended 1,000-hours intervals. The cost of the
petroleum-based lubricant is $5.00 per gallon. The total 8,000-hour
expenditure is $800.00 (20 gallons x $5.00 per gallon x 8 oil changes).
Now consider the cost for labor and
oil disposal associated with both machines. The oil in Machine A is
changed once in an 8,000-hour time span, If the oil change procedure
requires one man-hour of labor, the plant pays, say $50.00 for the hour
of labor, and $10.00 for disposal of the 20 gallons of oil (20 gallons x
disposal cost of $0.50 per gallon).
The oil in Machine B is changed every
1,000 hours, or 8 times within the 8,000 hours that Machine A is running
on synthetic lubricant. If each 8 oil changes requires an hour's labor,
the cost is $400.00 (8-hours x $50.00 per hour). Disposal of the 160
gallons of oil resulting from the 8 drains costs $80.00 (160 gallons x
$0.50 per gallon disposal cost). In addition, the plant may have lost
revenue due to down time during oil change -- 8 times as much for
Machine B as for Machine A.
Plant size plays an important role.
For a single machine such as discussed in the example, it may be very
difficult to justify the up-front investment and carrying costs of up to
$1,375.00 (55 gallons x $25.00 per gallon) for a 55 gallon drum of
synthetic lubricant alone. Even at 8,000 hours per oil change and
three-shift operation, the first 20 gallons would take nearly a year to
be consumed. Compare that with a total cost of $1,280.00 (including
labor and disposal) to lubricate the piece of equipment for 8,000 hours
with petroleum-based lubricant.
For a larger number of machines, the
situation reverses. The savings from using synthetic lubricant for 100
machines far outweigh the extra lubricant cost.
TABLE 2
COST COMPARISON
This breakdown of costs for maintaining two identical
items of equipment in a plastics extrusion plant illustrates savings
from using a synthetic lubricant. However, the considerable up-front
cost of synthetic (as much as $1,375.00 for a 55 gallon drum) means that
plant size (number of machines) also play a role in choosing the right
lubricant.
Parameter |
Machine A Synthetic |
Machine B Petroleum-Based |
|
A. Sump capacity |
20 gal. |
20 gal. |
B. Oil cost/gallon |
$25.00 |
$5.00 |
C. Oil changes/8000 hr. |
1 |
8 |
D. Lubricant cost/8000 hr (AxBxC) |
$500.00 |
$800.00 |
E. Labor hr/8000 hr (at 1 hr/oil change) |
1 |
8 |
F. Labor cost at 50/hr ($50 x E) |
$50.00 |
$400.00 |
G. Oil disposed/8000 hr (AxC) |
20 gal. |
160 gal. |
H. Lubricant disposal cost (at $0.50/gal.) |
$10.00 |
$80.00 |
|
|
Total expenditure (D+F+H) |
$560.00 |
$1,280.00 |